Do remember the following things:
Continuously be deferential towards local people, priests or Buddha images. You can wind up in prison on the off chance that you take a stab at being insolent towards Buddha pictures as they are sacrosanct in Thailand.
I know, it's hot and humid. Especially, for women, you would rather walk with your shorts and tank tops. However, that is not a very good idea if you are planning to visit temples or sacred places. At the very least, try to cover your knees and shoulders. Remember, this simple act shows that you respect the culture of the country.
It is again having to do with being respectful. As you can see respect is a huge thing in most Asian countries.
Don't forget to take off your shoes when you are entering someone's house or building which has a Buddha image within.
It won't be that hard to know how to say hello. Men say "Sawatdee-krap" and women say "Sawatdee-kah". Try to recognize the "wai" gesture. You as a foreigner are not expected to initiate the "wai" gesture, but if someone offers it first to you, try to return it back. However, never return a "wai" to a child, waiter, clerk, etc. Simply nod and smile in response.
Do not show any disrespect towards the locals, the royal family, monks, just never towards anybody.
It is a very disrespectful act, even if you mean it as a joke. Head is sacred in Thailand.
Especially in front of elderly or monks do not cross your legs. It applies whether you are sitting on the floor or in a chair.
Also, never point with your hand and never, never with one finger.
It is a taboo to touch the opposite sex in Public. Please refrain yourself from being too intimate or affectionate towards your partner in public.
As I have mentioned before, touching the opposite sex *is still a taboo in Thailand. A lot of people in Thailand still believe that a woman can lose her face if she is being touched publicly.
Unless you get special permission, it is strictly against the law to bring Buddha images out of the country. Of course, you can easily buy them there, but try to avoid unnecessary problem.
However, these are only some general things that you need to be aware of when you are in Thailand. I hope these do's and don'ts can help you in some ways. Enjoy your stay in Thailand.